World Journal of Scientific Research and Reviews

ISSN: 2334 - 0304

Vol. 4, No. 1, July 2016

Table of Contents

Articles


Schiff base [(N1Z,N2Z)-N1,N2-bis(1-phenylethylidene)ethane-1,2-diamine] with p-hydroxyphenyl telluriumtribromide and their metal complexes: synthesis and Characterization

Authors: Nuha H. Al-Saadawy, Allaa Kh. Ali and Huda J. Mohammed

Abstract

The reaction of aliphatic diamine [ethylene diamine] with acetophenone under showed conditions yielded Schiff base ligand. The another ligand (p-hydroxyphenyl telluriumtribromide) has been added to complexes. The structures of Cu(II), Ni(II), Co(II), Zn(II) and Fe(II) with schiff base compound and organotellurium ligand have been joined by the reacting between copper bromide, hydrate nickel chloride, hydrate cobalt chloride, zinc chloride, and iron bromide and two ligands in 1:2:2 mole ratio. The free ligands and their metal structures have been withdrawn in the solid state. The spectroscopic data of the structures suggest their 1:2:2 buildings structures which are inspected by elemental analysis (CHN), FT-IR, 1H NMR spectroscopy. The spectroscopic studies proposed the octahedral structure for the all structures and the results are represented and analyzed underneath.

Keywords: Complexes, organotellurium, metal complexes, ethylenediamine, acetophenone.

 


 

 

 

 

 

 

 

 

 

 

 

 

 

 

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